The results of studies on the synthesis, structure, thermochemistry and oxidising capacity of organic hydrotrioxides are generalised. Particular emphasis is placed on the analysis of thermal and catalytic decomposition of ROOOH and on generation of free radicals and singlet molecular oxygen. Problems concerning the mechanisms of formation and decomposition of organic hydrotrioxides are also considered. The bibliography includes 154 references.
V. V. Shereshovets (deceased), S. L. Khursan, V. D. Komissarov and G. A. Tolstikov, Russ. Chem. Rev., 2001, 70, 105 DOI: 10.1070/RC2001v070n02ABEH000622
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