Issue 11, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Inclusion by a diol host compound: structure and dynamics of volatile guest exchange

Mino R. Caira,a   Luigi R. Nassimbeni,*a   Fumio Todab  and  Dejana Vujovica  

* Corresponding authors

a Department of Chemistry, University of Cape Town, Rondebosch 7701, South Africa

b Department of Chemistry, Faculty of Science, Okayama University of Science, 1-1 Ridaicho, Okayama 700-0005, Japan

Abstract

1,1,6,6-Tetraphenylhexa-2,4-diyne-1,6-diol (H) forms inclusion compounds with furan (1 and 2), tetrahydrofuran (3) and thiophene (4). 1, H·½FUR (H ∶ G = 1 ∶ ½), is a true clathrate, with the furan guest located in a cage formed by the host. The remaining structures (H ∶ G = 1 ∶ 2) 2, H·2FUR, 3, H·2THF and 4, H·2THIO are isostructural with guests located in channels. Selectivity and guest exchange reactions have been analysed and correlated to the topologies of the inclusion compounds.

Graphical abstract: Inclusion by a diol host compound: structure and dynamics of volatile guest exchange

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Article information

DOI
https://doi.org/10.1039/B105248A
Article type
Paper
Submitted
14 Jun 2001
Accepted
08 Aug 2001
First published
24 Sep 2001

J. Chem. Soc., Perkin Trans. 2, 2001, 2119-2124

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Inclusion by a diol host compound: structure and dynamics of volatile guest exchange

M. R. Caira, L. R. Nassimbeni, F. Toda and D. Vujovic, J. Chem. Soc., Perkin Trans. 2, 2001, 2119 DOI: 10.1039/B105248A

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