Issue 5, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Aerobic oxidation of isopropanol catalysed by peroxovanadium complexes: mechanistic insights

Marcella Bonchio,a   Olga Bortolini,b   Valeria Conte*c  and  Silvia Primona  

* Corresponding authors

a CNR C. M. R. O., Dipartimento di Chimica Organica, via Marzolo 1, Padova, Italy

b Dipartimento di Chimica, via Borsari 46, Ferrara, Italy

c I.P.P.A. Facoltà di Agraria, Università di Foggia, Via Napoli 25, Foggia, Italy

Abstract

Aerobic oxidation of PriOH to acetone with parallel reduction of dioxygen to hydrogen peroxide is observed for acid PriOH–H2O solutions of peroxovanadates. Spectroscopic evidence, obtained with a combined use of 51V-NMR, UV–VIS and ESI-MS techniques, is presented for a monoperoxovanadium-catalysed inner-sphere oxidation of the alcohol coordinated to the metal center.

Graphical abstract: Aerobic oxidation of isopropanol catalysed by peroxovanadium complexes: mechanistic insights

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Article information

DOI
https://doi.org/10.1039/B009958I
Article type
Paper
Submitted
12 Dec 2000
Accepted
14 Mar 2001
First published
05 Apr 2001

J. Chem. Soc., Perkin Trans. 2, 2001, 763-765

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Aerobic oxidation of isopropanol catalysed by peroxovanadium complexes: mechanistic insights

M. Bonchio, O. Bortolini, V. Conte and S. Primon, J. Chem. Soc., Perkin Trans. 2, 2001, 763 DOI: 10.1039/B009958I

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