Issue 24, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Formation of adamantan-1-ols by the reactions of adamantanes with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) in trifluoromethanesulfonic acid

Kiyoshi Tanemura,*a   Tsuneo Suzuki,a   Yoko Nishida,a   Koko Satsumabayashia  and  Takaaki Horaguchib  

* Corresponding authors

a School of Dentistry at Niigata, The Nippon Dental University, Hamaura-cho, Niigata 951-8580, Japan
E-mail: tanemura@ngt.ndu.ac.jp

b Department of Chemistry, Faculty of Science, Niigata University, Ikarashi, Niigata 950-2181, Japan

Abstract

Adamantanes were treated with DDQ in trifluoromethanesulfonic acid followed by hydrolysis to give adamantan-1-ols in good yields.

Graphical abstract: Formation of adamantan-1-ols by the reactions of adamantanes with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) in trifluoromethanesulfonic acid

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Article information

DOI
https://doi.org/10.1039/B109548J
Article type
Communication
Submitted
19 Oct 2001
Accepted
01 Nov 2001
First published
16 Nov 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 3230-3231

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Formation of adamantan-1-ols by the reactions of adamantanes with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) in trifluoromethanesulfonic acid

K. Tanemura, T. Suzuki, Y. Nishida, K. Satsumabayashi and T. Horaguchi, J. Chem. Soc., Perkin Trans. 1, 2001, 3230 DOI: 10.1039/B109548J

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