Issue 24, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Palladium-catalyzed cyanation of bromocalix[4]arenes at the upper rim†

Hideaki Hioki,*a   Rumi Nakaoka,a   Aya Maruyamaa  and  Mitsuaki Kodamaa  

* Corresponding authors

a Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan
E-mail: hioki@ph.bunri-u.ac.jp

Abstract

Palladium-catalyzed cyanation of bromocalix[4]arenes possessing various kinds of functional groups at the lower rim is investigated. The yields varied depending on the functional groups. Most of the substrates are cyanated in excellent yield by treatment with Pd2(dba)3 or DPPF as the catalyst and Zn(CN)2 as the cyanide source.

Graphical abstract: Palladium-catalyzed cyanation of bromocalix[4]arenes at the upper rim

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Article information

DOI
https://doi.org/10.1039/B109083F
Article type
Paper
Submitted
09 Oct 2001
Accepted
06 Nov 2001
First published
27 Nov 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 3265-3268

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Palladium-catalyzed cyanation of bromocalix[4]arenes at the upper rim

H. Hioki, R. Nakaoka, A. Maruyama and M. Kodama, J. Chem. Soc., Perkin Trans. 1, 2001, 3265 DOI: 10.1039/B109083F

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