Issue 21, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Synthesis of (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl via nucleophilic aromatic substitution of (η6-fluorobenzene) chromium tricarbonyl

M. Rute G. da Costa,a   M. João M. Curto,a   Stephen G. Davies,*b   John Sandersc  and  Fátima C. Teixeiraab  

* Corresponding authors

a Instituto Nacional de Engenharia e Tecnologia Industrial, Departamento de Tecnologia de Indústrias Químicas, Estrada do Paço do Lumiar, 22, 1649-038 Lisboa, Portugal

b The Dyson Perrins Laboratory, University of Oxford, South Parks Road, Oxford, UK

c Chemical Crystallography Laboratory, University of Oxford, Parks Road, Oxford, UK

Abstract

Chiral hydroxylamine chromium tricarbonyl complexes may be prepared in satisfactory to reasonable yield via nucleophilic aromatic substitution of the anion derived from N,O-substituted hydroxylamines and (η6-fluorobenzene) chromium tricarbonyl. The enantiomerically pure complex (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl 6a was characterised by X-ray crystallography.

Graphical abstract: Synthesis of (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl via nucleophilic aromatic substitution of (η6-fluorobenzene) chromium tricarbonyl

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Article information

DOI
https://doi.org/10.1039/B107237B
Article type
Paper
Submitted
09 Aug 2001
Accepted
20 Sep 2001
First published
12 Oct 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 2850-2855

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Synthesis of (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl via nucleophilic aromatic substitution of (η6-fluorobenzene) chromium tricarbonyl

M. R. G. da Costa, M. J. M. Curto, S. G. Davies, J. Sanders and F. C. Teixeira, J. Chem. Soc., Perkin Trans. 1, 2001, 2850 DOI: 10.1039/B107237B

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