Issue 22, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Asymmetric synthesis of N-diphenylphosphinoylamines by solvent-free enantioselective addition of dialkylzincs to N-diphenylphosphinoylimines

Itaru Sato,a   Ryo Kodakaa  and  Kenso Soai*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Science, Science University of Tokyo, Kagurazaka, Shinjuku-ku, Tokyo, Japan
E-mail: ksoai@ch.kagu.sut.ac.jp
Fax: +81-3-3235-2214

Abstract

Solvent-free enantioselective addition of dialkylzincs to N-diphenylphosphinoylimines in the presence of chiral 2-morpholino-1-phenylpropan-1-ol affords N-diphenylphosphinoylamines with up to 97% ee. The reaction in the solvent-free system is faster than in organic solvents.

Graphical abstract: Asymmetric synthesis of N-diphenylphosphinoylamines by solvent-free enantioselective addition of dialkylzincs to N-diphenylphosphinoylimines

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Article information

DOI
https://doi.org/10.1039/B106775N
Article type
Communication
Submitted
26 Jul 2001
Accepted
04 Oct 2001
First published
15 Oct 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 2912-2914

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Asymmetric synthesis of N-diphenylphosphinoylamines by solvent-free enantioselective addition of dialkylzincs to N-diphenylphosphinoylimines

I. Sato, R. Kodaka and K. Soai, J. Chem. Soc., Perkin Trans. 1, 2001, 2912 DOI: 10.1039/B106775N

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