Depending upon the reaction conditions, intramolecular cycloadditions of variously substituted N-alkenoyl aryl azides 4 give the [1,2,3]triazolobenzodiazepine 5, bridgehead ![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
N double bond of the latter compounds is also exploited in the synthesis of [1,2,4]triazolobenzodiazepines 10 by means of nitrilimine cycloadditions.
L. Garanti, G. Molteni and G. Broggini, J. Chem. Soc., Perkin Trans. 1, 2001, 1816 DOI: 10.1039/B102686K
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