Issue 21, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Convenient preparations of polysubstituted 3H-pyrroles promoted by SmI2

Xiaoliang Xua  and  Yongmin Zhang*ab  

* Corresponding authors

a Department of Chemistry, Zhejiang University (Campus Xixi), Hangzhou, 310028, P.R. China
E-mail: yminzhang@mail.hz.zj.cn
Fax: + 86-0571-88807077

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, P.R. China

Abstract

The intermolecular reductive coupling of 1,1-diaryl-2,2-dicyanoethylenes or 1,1-diaryl-2-cyano-2-ethoxycarbonylethylenes with aromatic nitriles induced by samarium(II) iodide has been studied. Polysubstituted 3H-pyrroles were prepared in good to excellent yields under neutral and mild conditions.

Graphical abstract: Convenient preparations of polysubstituted 3H-pyrroles promoted by SmI2

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Article information

DOI
https://doi.org/10.1039/B102268G
Article type
Paper
Submitted
09 Mar 2001
Accepted
12 Sep 2001
First published
17 Oct 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 2836-2839

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Convenient preparations of polysubstituted 3H-pyrroles promoted by SmI2

X. Xu and Y. Zhang, J. Chem. Soc., Perkin Trans. 1, 2001, 2836 DOI: 10.1039/B102268G

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