Issue 18, 2001

Regio- and stereoselective synthesis of fluoroalkadienes using β-fluoroalkenyliodonium salt

Abstract

(E,E)-δ-Fluoro-α,β,γ,δ-unsaturated carbonyl compounds and (3E)-4-fluoro-1,3-dienes were stereoselectively synthesized by the palladium-catalyzed coupling reaction of (2-fluoroalkenyl)(p-tolyl)iodonium fluorides with α,β-unsaturated carbonyl compounds and tributylvinyltin, respectively.

Graphical abstract: Regio- and stereoselective synthesis of fluoroalkadienes using β-fluoroalkenyliodonium salt

Article information

Article type
Paper
Submitted
27 Feb 2001
Accepted
07 Aug 2001
First published
04 Sep 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 2283-2288

Regio- and stereoselective synthesis of fluoroalkadienes using β-fluoroalkenyliodonium salt

M. Yoshida, D. Nagahara, T. Fukuhara, N. Yoneda and S. Hara, J. Chem. Soc., Perkin Trans. 1, 2001, 2283 DOI: 10.1039/B101836L

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