Issue 9, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Indium-mediated allylation reactions of α-chlorocarbonyl compounds and preparation of allylic epoxides

Jeong Ah Shin,ab   Kyung Il Choi,a   Ae Nim Pae,a   Hun Yeong Koh,a   Han-Young Kangb  and  Yong Seo Choa  

a Biochemicals Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Korea
E-mail: ys4049@kist.re.kr
Fax: +82-2-958-5189

b Department of Chemistry, Chungbuk National University Cheongju, Chungbuk, Korea

Abstract

Indium-mediated allylation of α-chlorocarbonyl compounds with various allyl bromides in aqueous media gave the corresponding homoallylic chlorohydrins, which could be transformed into the corresponding epoxides in the presence of a base. These reactions were strongly dependent upon both the substituents at the carbon bearing chlorine and the allyl bromides used.

Graphical abstract: Indium-mediated allylation reactions of α-chlorocarbonyl compounds and preparation of allylic epoxides

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Article information

DOI
https://doi.org/10.1039/B101111L
Article type
Communication
Submitted
01 Feb 2001
Accepted
15 Mar 2001
First published
30 Mar 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 946-948

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Indium-mediated allylation reactions of α-chlorocarbonyl compounds and preparation of allylic epoxides

J. Ah Shin, K. I. Choi, A. N. Pae, H. Y. Koh, H. Kang and Y. S. Cho, J. Chem. Soc., Perkin Trans. 1, 2001, 946 DOI: 10.1039/B101111L

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