Issue 7, 2001

Synthesis and absolute configuration of stellettadine A, a bisguanidinium alkaloid isolated from a marine sponge Stelletta sp.

Abstract

Both the enantiomers of stellettadine A (1), a bisguanidinium alkaloid isolated from a marine sponge Stelletta sp., are synthesized by starting from (S )- and (R)-citronellal (2). The absolute configuration of naturally occurring 1 is established as R.

Graphical abstract: Synthesis and absolute configuration of stellettadine A, a bisguanidinium alkaloid isolated from a marine sponge Stelletta sp.

Article information

Article type
Paper
Submitted
02 Jan 2001
Accepted
16 Feb 2001
First published
19 Mar 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 657-661

Synthesis and absolute configuration of stellettadine A, a bisguanidinium alkaloid isolated from a marine sponge Stelletta sp.

H. Takikawa, D. Nozawa and K. Mori, J. Chem. Soc., Perkin Trans. 1, 2001, 657 DOI: 10.1039/B100206F

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