Issue 10, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Convenient synthesis of optically active 1,2-diol monosulfonates and terminal epoxidesvia oxazaborolidine-catalyzed asymmetric boranereduction of α-sulfonyloxy ketones

Byung Tae Cho,*a   Weon Ki Yanga  and  Ok Kyung Choia  

* Corresponding authors

a Department of Chemistry, Hallym University, Chunchon, Kangwondo, Republic of Korea

Abstract

A very convenient asymmetric synthesis of 1,2-diol monosulfonates and terminal epoxides with high optical purity via oxazaborolidine-catalyzed asymmetric borane reduction of α-sulfonyloxy ketones using N-ethyl-N-isopropylaniline–borane complex as borane carrier has been developed.

Graphical abstract: Convenient synthesis of optically active 1,2-diol monosulfonates and terminal epoxides via oxazaborolidine-catalyzed asymmetric borane reduction of α-sulfonyloxy ketones

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Article information

DOI
https://doi.org/10.1039/B010155I
Article type
Paper
Submitted
14 Dec 2000
Accepted
23 Mar 2001
First published
02 May 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 1204-1211

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Convenient synthesis of optically active 1,2-diol monosulfonates and terminal epoxides via oxazaborolidine-catalyzed asymmetric borane reduction of α-sulfonyloxy ketones

B. T. Cho, W. K. Yang and O. K. Choi, J. Chem. Soc., Perkin Trans. 1, 2001, 1204 DOI: 10.1039/B010155I

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