Issue 11, 2001
From the journal:

New Journal of Chemistry

A concise and chemoenzymatic synthesis of (−)-gabosine A, a carba-sugar enone from Streptomycetes

Martin G. Banwell,*a   Andrew M. Brayb  and  David J. Wonga  

* Corresponding authors

a Research School of Chemistry, Institute of Adanced Studies, The Australian National Uniersity, Canberra, Australia
E-mail: mgb@rsc.anu.edu.au

b Mimotopes Pty Ltd, 11 Duerdin Street, Clayton, Victoria, Australia

Abstract

The title compound 1 has been prepared, for the first time, in six steps and a completely stereo-controlled fashion from the cis-1,2-dihydrocatechol 3. The starting material is a readily available and enantiopure compound that can be obtained in large quantity [italic v (to differentiate from Times ital nu)]ia toluene dioxygenase (TDO) mediated dihydroxylation of iodobenzene.

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Article information

DOI
https://doi.org/10.1039/B106419C
Article type
Letter
Submitted
19 Jul 2001
Accepted
21 Aug 2001
First published
15 Oct 2001

New J. Chem., 2001,25, 1351-1354

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A concise and chemoenzymatic synthesis of (−)-gabosine A, a carba-sugar enone from Streptomycetes

M. G. Banwell, A. M. Bray and D. J. Wong, New J. Chem., 2001, 25, 1351 DOI: 10.1039/B106419C

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