Issue 7, 2001
From the journal:

New Journal of Chemistry

A novel photo atom transfer radical polymerization of methyl methacrylate

Shu-Hui Qin,a   Dong-Qi Qina  and  Kun-Yuan Qiu*a  

* Corresponding authors

a Department of Polymer Science and Engineering, College of Chemistry and Molecular Engineering, Chemistry Building, Peking Uniersity, Beijing, China
E-mail: kyqiu@chem.pku.edu.cn

Abstract

Photo atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) was realized with a novel photo initiating system, 2,2-dimethoxy-2-phenylacetophenone (DMPA)/ferric tri(N,N-diethyldithiocarbamate) [Fe(dtc)3], which proceeds with DPMA as the photo initiator, Fe(dtc)3 as the catalyst and dtc as a reversible transfer group, and is halogen and ligand free; well-defined polyMMA was prepared and the polymerization was found to involve a reverse ATRP mechanism.

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Article information

DOI
https://doi.org/10.1039/B103908N
Article type
Letter
Submitted
01 May 2001
Accepted
04 May 2001
First published
14 Jun 2001

New J. Chem., 2001,25, 893-895

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A novel photo atom transfer radical polymerization of methyl methacrylate

S. Qin, D. Qin and K. Qiu, New J. Chem., 2001, 25, 893 DOI: 10.1039/B103908N

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