Issue 3, 2001
From the journal:

New Journal of Chemistry

Organic–inorganic hybrid cyclic aggregate or 2D network assembled by silver(I) 3,5-dinitrobenzoate with 2-methylimidazole or 2-aminopyrimidine

An-Wu Xu,a   Cheng-Yong Su,*a   Ze-Fu Zhang,b   Yue-Peng Caia  and  Chun-Long Chena  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Zhongshan Uniersity, Guangzhou, China
E-mail: cesscy@zsu.edu.cn

b Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China

Abstract

Silver(I) 3,5-dinitrobenzoate (DNB) reacts with 2-methylimidazole (MeIm), producing a linearly coordinated [Ag(MeIm)2]+ cation that is further assembled with 3,5-dinitrobenzoate anion [italic v (to differentiate from Times ital nu)]ia N–H···O hydrogen bonding to give the cyclic aggregate {[Ag(MeIm)2](DNB)}21; whereas with 2-aminopyrimidine (APym) it affords the coordination polymer [Ag(Apym)(DNB)]∞ 2, which is assembled into a two-dimensional network sustained by weak C–H···O hydrogen bonds.

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Article information

DOI
https://doi.org/10.1039/B008383F
Article type
Paper
Submitted
02 Oct 2000
Accepted
05 Dec 2000
First published
15 Feb 2001

New J. Chem., 2001,25, 479-482

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Organic–inorganic hybrid cyclic aggregate or 2D network assembled by silver(I) 3,5-dinitrobenzoate with 2-methylimidazole or 2-aminopyrimidine

A. Xu, C. Su, Z. Zhang, Y. Cai and C. Chen, New J. Chem., 2001, 25, 479 DOI: 10.1039/B008383F

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