Issue 2, 2001
From the journal:

New Journal of Chemistry

First structurally characterised metal complex of a 2H-benzimidazole derivative. Copper mediated synthesis of 2,2-dimethyl-2H-benzimidazole from 1,2-phenylenediamine and acetone

Sanchita Hati,a   Goutam K. Patra,a   Jnan P. Naskar,a   Michael G. B. Drewb  and  Dipankar Datta*a  

* Corresponding authors

a Department of Inorganic Chemistry, Indian Association for the Cultiation of Science, Calcutta, India
E-mail: icdd@mahendra.iacs.res.in

b Department of Chemistry, Uniersity of Reading, Whiteknights, Reading, UK

Abstract

2,2-Dimethyl-2H-benzimidazole (1) was synthesised by exploiting the reaction of acetone with bis(1,2-phenylenediamine)copper(II) perchlorate. Additionally, the X-ray crystal structure of [CuI(1)(PPh3)2]ClO4 is reported.

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Article information

DOI
https://doi.org/10.1039/B007410L
Article type
Letter
Submitted
08 Sep 2000
Accepted
07 Nov 2000
First published
04 Jan 2001

New J. Chem., 2001,25, 218-220

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First structurally characterised metal complex of a 2H-benzimidazole derivative. Copper mediated synthesis of 2,2-dimethyl-2H-benzimidazole from 1,2-phenylenediamine and acetone

S. Hati, G. K. Patra, J. P. Naskar, M. G. B. Drew and D. Datta, New J. Chem., 2001, 25, 218 DOI: 10.1039/B007410L

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