The prototropic rearrangement equilibrium of fluorine-substituted hypophosphoric acid dimethylamides in a gas phase has been found to be displaced towards the formation of a three-coordinated phosphorus atom, in contrast to the rearrangement of dimethyl phosphite derivatives.
V. M. Mamaev, A. V. Prisyajnuk, L. S. Logutenko and Y. V. Babin, Mendeleev Commun., 2001, 11, 221 DOI: 10.1070/MC2001v011n06ABEH001418
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