Issue 6, 2001

Octacoordinated main-group element centres in a planar cyclic B8 environment: an ab initio study

Abstract

Density functional theory [B3LYP/6-311G(2df)] calculations predict stable planar structures of the nonclassical compounds XB8 (X = Si, P+) containing central octacoordinated silicon and phosphorus atoms, and a fluxional structure of CB8 with effective octacoordination of the carbon atom.

Article information

Article type
Paper

Mendeleev Commun., 2001,11, 213-214

Octacoordinated main-group element centres in a planar cyclic B8 environment: an ab initio study

R. M. Minyaev, T. N. Gribanova, A. G. Starikov and V. I. Minkin, Mendeleev Commun., 2001, 11, 213 DOI: 10.1070/MC2001v011n06ABEH001496

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