Issue 10, 2001
From the journal:

Journal of Materials Chemistry

Masaki Matsuda,a   Toshio Naito,a   Tamotsu Inabe,*a   Noriaki Hanasakib  and  Hiroyuki Tajimab  

* Corresponding authors

a Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo, Japan
E-mail: inabe@sci.hokudai.ac.jp

b Institute for Solid State Physics, The University of Tokyo, Kashiwanoha, Kashiwa, Chiba, Japan

Abstract

Electrochemical oxidation of PTMA[MIII(Pc)(CN)2] (PTMA = phenyltrimethylammonium, Pc = phthalocyaninato, and M = Co or Fe) gives partially oxidized salts (PTMA)x[MIII(Pc)(CN)2]·y(solvent) (solvent = acetonitrile or acetone). The obtained crystals in which the solvent molecules partially occupy the cationic sites are isomorphous regardless of M and solvent. They are highly conducting and metallic behavior is observed in the conductivity and thermoelectric power measurements. In contrast to the Pauli-like behavior of the CoIII salt, Curie-like behavior with an anomaly due to antiferromagnetic interactions was observed for the FeIII salt in magnetic susceptibility measurements. The existence of local magnetic moments in the FeIII salt leads to a significant influence on the transport properties, suggesting the existence of π–d interactions in this system.

Graphical abstract: Structure and electrical and magnetic properties of (PTMA)x[M(Pc)(CN)2]·y(solvent)  (PTMA = phenyltrimethylammonium and [M(Pc)(CN)2] = dicyano(phthalocyaninato)Miii with M = Co and Fe). Partial oxidation by partial solvent occupation of the cationic site

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B100623L
Article type
Paper
Submitted
17 Jan 2001
Accepted
26 Jun 2001
First published
21 Aug 2001

J. Mater. Chem., 2001,11, 2493-2497

Permissions

Request permissions

Structure and electrical and magnetic properties of (PTMA)x[M(Pc)(CN)2]·y(solvent)  (PTMA = phenyltrimethylammonium and [M(Pc)(CN)2] = dicyano(phthalocyaninato)MIII with M = Co and Fe). Partial oxidation by partial solvent occupation of the cationic site

M. Matsuda, T. Naito, T. Inabe, N. Hanasaki and H. Tajima, J. Mater. Chem., 2001, 11, 2493 DOI: 10.1039/B100623L

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements