Issue 3, 2001
From the journal:

Green Chemistry

Solvent-free ruthenium-catalysed vinylcarbamate synthesis from phenylacetylene and diethylamine in ‘supercritical’ carbon dioxide

Markus Rohr,a   Christian Geyer,a   Roland Wandeler,a   Michael S. Schneider,a   Eamonn F. Murphya  and  Alfons Baiker*a  

* Corresponding authors

a Laboratory of Technical Chemistry, Swiss Federal Institute of Technology, ETH-Zentrum, CH-8092, Zürich, Switzerland.
E-mail: baiker@tech.chem.ethz.ch

Abstract

The solvent-free synthesis of β-[(diethylcarbamoyl)oxy]styrene from phenylacetylene and diethylamine in supercritical carbon dioxide is greatly accelerated for a series of ruthenium catalysts compared to the same reactions in toluene.

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Article information

DOI
https://doi.org/10.1039/B102341C
Article type
Paper
Submitted
13 Mar 2001
First published
24 Apr 2001

Green Chem., 2001,3, 123-125

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Solvent-free ruthenium-catalysed vinylcarbamate synthesis from phenylacetylene and diethylamine in ‘supercritical’ carbon dioxide

M. Rohr, C. Geyer, R. Wandeler, M. S. Schneider, E. F. Murphy and A. Baiker, Green Chem., 2001, 3, 123 DOI: 10.1039/B102341C

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