Issue 24, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Formation of [M(15-crown-5)2]2[Li(NHPy)3] (M = K or Cs): the first structurally authenticated examples of a monomeric lithium species coordinated by three amide anions

Stephen T. Liddlea  and  William Clegg*a  

* Corresponding authors

a Department of Chemistry, University of Newcastle upon Tyne, Newcastle upon Tyne, UK
E-mail: w.clegg@ncl.ac.uk

Abstract

The title compounds crystallise as solvent-separated ion triplets incorporating the first structurally authenticated examples of a monomeric species with lithium coordinated by three rather than two amide anions; the compounds, products of a heavier alkali metal mediated ligand cleavage reaction, can be viewed as the products of an incomplete metathesis reaction due to their heterobimetallic nature.

Graphical abstract: Formation of [M(15-crown-5)2]2[Li(NHPy)3] (M = K or Cs): the first structurally authenticated examples of a monomeric lithium species coordinated by three amide anions

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Article information

DOI
https://doi.org/10.1039/B109903P
Article type
Communication
Submitted
30 Oct 2001
Accepted
14 Nov 2001
First published
23 Nov 2001

J. Chem. Soc., Dalton Trans., 2001, 3549-3550

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Formation of [M(15-crown-5)2]2[Li(NHPy)3] (M = K or Cs): the first structurally authenticated examples of a monomeric lithium species coordinated by three amide anions

S. T. Liddle and W. Clegg, J. Chem. Soc., Dalton Trans., 2001, 3549 DOI: 10.1039/B109903P

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