Issue 23, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

A new carbonate bridged tetranuclear zinc(ii) complex of an asymmetric tetrapodal compartmental ligand

Harry Adams,a   Darren Bradshawa  and  David E. Fenton*a  

* Corresponding authors

a Department of Chemistry, Dainton Building, The University of Sheffield, Sheffield, UK
E-mail: d.fenton@sheffield.ac.uk

Abstract

A zinc(II) complex of the asymmetric tetrapodal proligand 2-{[bis(2-pyridinylmethyl)amino]methyl}-6-[{[(2-hydroxyphenyl)methyl](2-pyridinylmethyl)amino}methyl]-4-methylphenol reacts with carbon dioxide to give the tetranuclear zinc(II) complex [Zn4L2(CO3)](BF4)2·5CH3OH·4H2O; the crystal structure of this complex revealed an unusual μ3-binding mode of the carbonate to one mononuclear zinc atom and a dinuclear pair of zinc atoms.

Graphical abstract: A new carbonate bridged tetranuclear zinc(ii) complex of an asymmetric tetrapodal compartmental ligand

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Article information

DOI
https://doi.org/10.1039/B108432C
Article type
Communication
Submitted
17 Sep 2001
Accepted
18 Oct 2001
First published
29 Oct 2001

J. Chem. Soc., Dalton Trans., 2001, 3407-3409

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A new carbonate bridged tetranuclear zinc(II) complex of an asymmetric tetrapodal compartmental ligand

H. Adams, D. Bradshaw and D. E. Fenton, J. Chem. Soc., Dalton Trans., 2001, 3407 DOI: 10.1039/B108432C

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