Linkage of heteronuclear rhodium–platinum clusters†
Abstract
Two coupled clusters [Rh8Pt2(CO)21(dppm)2] (1) and [Rh6Pt4(CO)16(dppm)3] (2) have been synthesised and characterised; the mixed metal Rh2Pt2 cluster in 1 and the tetranuclear Pt4 cluster in 2 are bonded to the Rh6 metal core via Rh–Rh and Pt–Rh bonds.
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