Mixing solutions of homoleptic cobalt(II) complexes [CoA2]2+ and [CoB2]2+ results in the establishment of a combinatorial library containing the heteroleptic complex [CoAB]2+. By using enantiomorphic ligands A and B the reactions may be followed by 1H NMR spectroscopy. Exchange reactions with 6-substituted ligands are slower than those with 5- and 4′-substituted species.
E. C. Constable, C. E. Housecroft, T. Kulke, C. Lazzarini, E. R. Schofield and Y. Zimmermann, J. Chem. Soc., Dalton Trans., 2001, 2864 DOI: 10.1039/B104865C
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