Issue 21, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

A new heterometalate anion [GdMo6(CH3CHOCOO)6O15]3− with a nine-coordinate gadolinium encapsulated at the center

Chuan-De Wu,a   Can-Zhong Lu,*a   Jia-Cheng Liu,a   Hong-Hui Zhuanga  and  Jin-Shun Huang*a  

* Corresponding authors

a The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: czlu@ms.fjirsm.ac.cn

Abstract

The reaction of an acetonitrile solution of ammonium molybdate with gadolinium chloride in the presence of lactic acid gives rise to the formation of a spherical cluster anion containing six Mo atoms with a Gd(III) encapsulated at the center, [GdMo6(CH3CHOCOO)6O15]3−  1, which is further linked to a three-dimensional network by ammonium ions via hydrogen bonding. The magnetic properties of the complex have been studied by measuring its magnetic susceptibility at various temperatures in the 5–300 K range. The results are consistent with room temperature EPR data.

Graphical abstract: A new heterometalate anion [GdMo6(CH3CHOCOO)6O15]3− with a nine-coordinate gadolinium encapsulated at the center

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Article information

DOI
https://doi.org/10.1039/B102926F
Article type
Paper
Submitted
30 Mar 2001
Accepted
11 Sep 2001
First published
15 Oct 2001

J. Chem. Soc., Dalton Trans., 2001, 3202-3204

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A new heterometalate anion [GdMo6(CH3CHOCOO)6O15]3− with a nine-coordinate gadolinium encapsulated at the center

C. Wu, C. Lu, J. Liu, H. Zhuang and J. Huang, J. Chem. Soc., Dalton Trans., 2001, 3202 DOI: 10.1039/B102926F

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