Issue 5, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Structural isomerism in R3PSe(Ph)I compounds: the ionic structure of [(Me2N)3PSePh]I

Stephen M. Godfrey,a   Ruth T. A. Ollerenshaw,a   Robin G. Pritcharda  and  Claire L. Richardsa  

a Department of Chemistry, University of Manchester Institute of Science and Technology, Manchester, UK
E-mail: Stephen.m.godfrey@umist.ac.uk

Abstract

The reaction of two mole equivalents of (Me2N)3P with Ph2Se2I2 produces the ionic compound [(Me2N)3PSePh]I which contains a long Se–I contact, 3.825(1) Å, and a bent P–Se–I angle, 114.5(2)°.

Graphical abstract: Structural isomerism in R3PSe(Ph)I compounds: the ionic structure of [(Me2N)3PSePh]I

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Article information

DOI
https://doi.org/10.1039/B100882J
Article type
Communication
Submitted
24 Jan 2001
Accepted
24 Jan 2001
First published
09 Feb 2001

J. Chem. Soc., Dalton Trans., 2001, 508-509

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Structural isomerism in R3PSe(Ph)I compounds: the ionic structure of [(Me2N)3PSePh]I

S. M. Godfrey, R. T. A. Ollerenshaw, R. G. Pritchard and C. L. Richards, J. Chem. Soc., Dalton Trans., 2001, 508 DOI: 10.1039/B100882J

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