Issue 7, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Tetranuclear iron(III) carboxylate clusters with 1,10-phenanthroline and 2,2′-bipyridine: a new [Fe4(μ4-OHO)(μ-OH)2]7+ core

Athanassios K. Boudalis,a   Nikolia Lalioti,b   Georgios A. Spyroulias,c   Catherine P. Raptopoulou,d   Aris Terzis,d   Vassilis Tangoulis †*b  and  Spyros P. Perlepes*a  

* Corresponding authors

a Department of Chemistry, University of Patras, Patras, Greece
E-mail: perlepes@patreas.upatras.gr

b Department of Chemistry, University of Florence, via Maragliano 75/77, Florence, Italy

c Department of Pharmacy, University of Patras, Patras, Greece

d Institute of Materials Science, NCSR “Demokritos”, Aghia Paraskevi Attikis, Greece

Abstract

The reactions between Fe(ClO4)3·6H2O, NaO2CMe·3H2O and L–L (L–L = 2,2′-bipyridine, 1,10-phenanthroline) in MeCN give complexes [Fe4(OHO)(OH)2(O2CMe)4(L–L)4](ClO4)3 whose cations contain the novel [Fe4(μ4-OHO)(μ-OH)2]7+ core; magnetic studies indicate that both complexes have S = 0 ground states, consistent with the presence of strong antiferromagnetic exchange interactions.

Graphical abstract: Tetranuclear iron(III) carboxylate clusters with 1,10-phenanthroline and 2,2′-bipyridine: a new [Fe4(μ4-OHO)(μ-OH)2]7+ core

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Article information

DOI
https://doi.org/10.1039/B100854O
Article type
Communication
Submitted
24 Jan 2001
Accepted
05 Mar 2001
First published
15 Mar 2001

J. Chem. Soc., Dalton Trans., 2001, 955-957

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Tetranuclear iron(III) carboxylate clusters with 1,10-phenanthroline and 2,2′-bipyridine: a new [Fe4(μ4-OHO)(μ-OH)2]7+ core

A. K. Boudalis, N. Lalioti, G. A. Spyroulias, C. P. Raptopoulou, A. Terzis, V. Tangoulis<img border="0" src="https://www.rsc.org/images/entities/char_200a.gif" alt=" " xmlns="http://www.rsc.org/schema/rscart38" /> and S. P. Perlepes, J. Chem. Soc., Dalton Trans., 2001, 955 DOI: 10.1039/B100854O

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