Issue 7, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Aqueous hypervalent silicon complexes with aliphatic sugar acids

Stephen D. Kinrade,*a   Robin J. Hamilton,a   Andrew S. Schacha  and  Christopher T. G. Knightb  

* Corresponding authors

a Dept. of Chemistry, Lakehead University, 955 Oliver Road, Thunder Bay, Ontario, Canada
E-mail: Stephen.Kinrade@lakeheadu.ca

b School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, USA

Abstract

Silicon-29 and carbon-13 NMR spectroscopy is employed to determine the structures of stable five- and six-coordinated organosilicon complexes formed by the addition of certain aliphatic acid carbohydrates (such as gluconic acid, glucoheptonic acid and saccharic acid) to aqueous alkaline silicate solutions.

Graphical abstract: Aqueous hypervalent silicon complexes with aliphatic sugar acids

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Article information

DOI
https://doi.org/10.1039/B010111G
Article type
Communication
Submitted
19 Dec 2000
Accepted
19 Feb 2001
First published
08 Mar 2001

J. Chem. Soc., Dalton Trans., 2001, 961-963

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Aqueous hypervalent silicon complexes with aliphatic sugar acids

S. D. Kinrade, R. J. Hamilton, A. S. Schach and C. T. G. Knight, J. Chem. Soc., Dalton Trans., 2001, 961 DOI: 10.1039/B010111G

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