Tetrakis(4-aminopyridine)diisothiocyanatonickel(II) and its clathrates with EtOH, Me2CO and DMSO: structures, thermal stabilities and guest exchange

Luigi R. Nassimbeni; Mairi L. Kilkenny

doi:10.1039/B010042K

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Tetrakis(4-aminopyridine)diisothiocyanatonickel(II) and its clathrates with EtOH, Me₂CO and DMSO: structures, thermal stabilities and guest exchange†

Luigi R. Nassimbeni*^a and Mairi L. Kilkenny^a

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^a Department of Chemistry, University of Cape Town, Rondebosch, South Africa

Abstract

The structures of the Werner complex, Ni(NCS)₂(4-NH₂-py)₄ as the apohost, 1, and its inclusion compounds with EtOH/Me₂CO, 2, and DMSO, 3, have been elucidated. The dynamics of guest exchange between the clathrates have been monitored by DSC. The inclusion compounds can be formed by exposing the host to vapour of the guest, and powder XRD shows this reaction to be fully reversible.

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Article information

DOI: https://doi.org/10.1039/B010042K
Article type: Paper
Submitted: 15 Dec 2000
Accepted: 26 Feb 2001
First published: 27 Mar 2001

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J. Chem. Soc., Dalton Trans., 2001, 1172-1175

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Tetrakis(4-aminopyridine)diisothiocyanatonickel(II) and its clathrates with EtOH, Me₂CO and DMSO: structures, thermal stabilities and guest exchange

L. R. Nassimbeni and M. L. Kilkenny, J. Chem. Soc., Dalton Trans., 2001, 1172 DOI: 10.1039/B010042K

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Journal of the Chemical Society, Dalton Transactions