Issue 6, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

In situ ligand synthesis and the first crystallographically characterized lanthanide 3-D pillared networks containing benzene-1,4-disulfonate as a building block †

Ren-Gen Xiong,a   Jing Zhang,a   Zhen-Feng Chen,a   Xiao-Zeng You,*a   Chi-Ming Cheb  and  Hoong-Kun Func  

* Corresponding authors

a Coordination Chemistry Institute, the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, P. R. China

b Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong

c X-Ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, Penang, Malaysia

Abstract

The reaction of Eu(NO3)3·6H2O with 4-sulfobenzoic acid (4-H2SB) yields an unprecedented pillar-like 3-D network, Eu2(1,4-BDS)(4-SB)2·3H2O (1) in which benzene-1,4-disulfonate (1,4-BDS) was synthesized in situ; 1 displays very high thermal stability (stable up to 573 °C) and a strong red fluorescence emission in the solid-state, Gd2(1,4-BDS)(4-SB)2·3H2O (2) was also prepared.

Graphical abstract: In situ ligand synthesis and the first crystallographically characterized lanthanide 3-D pillared networks containing benzene-1,4-disulfonate as a building block [ ]

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B009542G
Article type
Communication
Submitted
28 Nov 2000
Accepted
08 Feb 2001
First published
19 Feb 2001

J. Chem. Soc., Dalton Trans., 2001, 780-782

Permissions

Request permissions

In situ ligand synthesis and the first crystallographically characterized lanthanide 3-D pillared networks containing benzene-1,4-disulfonate as a building block

R. Xiong, J. Zhang, Z. Chen, X. You, C. Che and H. Fun, J. Chem. Soc., Dalton Trans., 2001, 780 DOI: 10.1039/B009542G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements