Coordination chemistry, reactivities, and stereoelectronic properties of chelating phosphine ligands containing thioamide substituents
Abstract
The intramolecular exo-cycloaddition reaction between )-(1-(dimethylamino)ethyl)naphthalene as the chiral auxiliary gave the corresponding thioamide-substituted P-chiral phosphanorbornene stereospecifically in 6 d. The exo-cycloadduct coordinated to the palladium template as a bidentate chelate via its phosphorus and thioamide-sulfur donor atoms. The corresponding intermolecular endo-cycloaddition reaction using the analogous chloropalladium template containing the same ortho-metallated
S bond in these sterically hindered chelates are unreactive toward cycloaddition reaction with the