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Issue 21, 2001
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Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex

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Abstract

2-Pyridylmethylimidazolium salts and IrH5(PPh3)2 give an [(N–C)IrH2(PPh3)2]+ species with the imidazole ring bound in the ‘wrong way’: at C-5, not at the expected C-2.

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Article information


Submitted
24 Aug 2001
Accepted
24 Sep 2001
First published
18 Oct 2001

Chem. Commun., 2001, 2274-2275
Article type
Communication

Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex

S. Gründemann, A. Kovacevic, M. Albrecht, J. W. Faller Robert and H. Crabtree, Chem. Commun., 2001, 2274
DOI: 10.1039/B107881J

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