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Issue 18, 2001
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Platinum- and palladium-catalysed Kocheshkov redistribution of dialkyltin dichlorides or tetraalkyltins with tin tetrachloride

Sander Thoonen,a  Berth-Jan Deelman*ab  and  Gerard van Kotena 
Author affiliations

* Corresponding authors

a Debye Institute, Department of Metal-Mediated Synthesis, Utrecht University, Padualaan 8, 3584 CH, Utrecht, The Netherlands

b ATOFINA Vlissingen B.V., PO Box 70, 4380 AB, Vlissingen, The Netherlands.
E-mail: b.j.deelman@chem.uu.nl

Abstract

The Kocheshkov redistribution reaction of tetraalkyltin or dialkyltin dichlorides with tin tetrachloride is effectively catalysed by platinum(II) or palladium(II) phosphine complexes, yielding alkyltin trichlorides in high yield and with high selectivity.

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Publication details

The article was received on 10 Jul 2001, accepted on 13 Aug 2001 and first published on 05 Sep 2001


Article type: Communication
DOI: 10.1039/B106082C
Citation: Chem. Commun., 2001,0, 1840-1841

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    Platinum- and palladium-catalysed Kocheshkov redistribution of dialkyltin dichlorides or tetraalkyltins with tin tetrachloride

    S. Thoonen, B. Deelman and G. van Koten, Chem. Commun., 2001, 0, 1840
    DOI: 10.1039/B106082C

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