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Issue 8, 2001
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Enantioselective synthesis of bicyclic compounds via catalytic 1,4-addition-ring closing metathesisElectronic supplementary information (ESI) available: NMR spectra and detailed explanation. See http://www.rsc.org/suppdata/cc/b1/b100283j/

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Abstract

A novel three step asymmetric annulation procedure comprises a tandem catalytic enantioselective 1,4-addition-allylic substitution, Grignard addition and ring closing metathesis (RCM) sequence to provide [6,6], [7,6], [8,6] and [6,7] bicyclic products with ee’s of 93–97% in which the size of both rings can easily be varied independent of each other.

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Publication details

The article was received on 08 Jan 2001, accepted on 08 Mar 2001 and first published on 30 Mar 2001


Article type: Communication
DOI: 10.1039/B100283J
Chem. Commun., 2001, 735-736

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    Enantioselective synthesis of bicyclic compounds via catalytic 1,4-addition-ring closing metathesis

    R. Naasz, L. A. Arnold, A. J. Minnaard and B. L. Feringa, Chem. Commun., 2001, 735
    DOI: 10.1039/B100283J

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