Issue 24, 2001

Ditopic azathioether macrocycles as hosts for transition metal salts

Abstract

The synthesis and complexation of two heteroditopic lariat azathioether macrocycles L1 and L2 incorporating acylurea functionalised pendant arms are described; L1 and L2 are capable of simultaneously binding both the cationic and anionic moieties of a metal salt as confirmed by the structures of [PdCl2(L1)], [CuCl(L2)]2CuCl4 and [Ag(NO3)(L2)] and by 1H NMR studies in solution on [Ag(NO3)(L2)].

Supplementary files

Article information

Article type
Communication
Submitted
17 Oct 2001
Accepted
14 Nov 2001
First published
06 Dec 2001

Chem. Commun., 2001, 2678-2679

Ditopic azathioether macrocycles as hosts for transition metal salts

J. B. Love, J. M. Vere, M. W. Glenny, A. J. Blake and M. Schröder, Chem. Commun., 2001, 2678 DOI: 10.1039/B109486F

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