Issue 23, 2001

Diastereo- and enantioselective synthesis of α,β-disubstituted γ-nitro methyl sulfonatesDedicated to Professor Helmut Zahn on the occasion of his 85th birthday.

Abstract

A novel asymmetric synthesis of highly enantioenriched homotaurine precursors has been developed via diastereoselective Michael addition of lithiated enantiopure sulfonates to nitroalkenes by using 1,2∶5,6-di-O-isopropylidene-α-D-allofurano se as chiral auxiliary.

Supplementary files

Article information

Article type
Communication
Submitted
24 Sep 2001
Accepted
22 Oct 2001
First published
15 Nov 2001

Chem. Commun., 2001, 2498-2499

Diastereo- and enantioselective synthesis of α,β-disubstituted γ-nitro methyl sulfonates

D. Enders, O. M. Berner, N. Vignola and J. W. Bats, Chem. Commun., 2001, 2498 DOI: 10.1039/B108567K

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