Issue 24, 2001
From the journal:

Chemical Communications

1,2,9,10,17,18,25,26,27,28,35,36,37,38,39,40-Hexadecasila[28](1,2,4,5)-cyclophane and its open-chain homologs

Soichiro Kyushin,a   Tsukasa Kitahara,a   Ryoji Tanaka,a   Masanori Takeda,a   Takeshi Matsumotoa  and  Hideyuki Matsumoto*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Gunma University, Kiryu, Gunma, Japan.
E-mail: matumoto@chem.gunma-u.ac.jp;
Fax: +81-277-30-1291;
Tel: +81-277-30-1290

Abstract

The metathesis of the Si–Si bonds of benzo[1,2∶4,5]-bis(1,1,2,2-tetramethyl-1,2-disilacyclobut-3-ene) with Pd(PPh3)4 gave 1,2,9,10,17,18,25,26,27,28,35,36,37,38,39,40- hexadecasila[28](1,2,4,5)cyclophane and its open-chain homologs, in which the σ–π conjugation is extended all over the molecule.

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Article information

DOI
https://doi.org/10.1039/B107706F
Article type
Communication
Submitted
29 Aug 2001
Accepted
06 Nov 2001
First published
06 Dec 2001

Chem. Commun., 2001, 2714-2715

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1,2,9,10,17,18,25,26,27,28,35,36,37,38,39,40-Hexadecasila[28](1,2,4,5)-cyclophane and its open-chain homologs

S. Kyushin, T. Kitahara, R. Tanaka, M. Takeda, T. Matsumoto and H. Matsumoto, Chem. Commun., 2001, 2714 DOI: 10.1039/B107706F

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