Issue 21, 2001
From the journal:

Chemical Communications

Efficient and selective catalytic oxidative cleavage of α-hydroxy ketones using vanadium-based HPA and dioxygen

Leïla El Aakel,ab   Franck Launay,*a   Ahmed Atlamsanib  and  Jean-Marie Brégeaulta  

* Corresponding authors

a Laboratoire des Systèmes Interfaciaux à l’Echelle Nanométrique, Université Pierre et Marie Curie, unité CNRS 2312, case 196, 4 place Jussieu, 75252 Paris cedex 05, France
E-mail: flaunay@ccr.jussieu.fr
Fax: 33 (0)1 44 27 55 36

b Laboratoire de Chimie Physique Appliquée, Département de Chimie, Faculté des Sciences, Université Abdelmalek-Essaadi, BP2121, 93000 Tétouan, Morocco

Abstract

The combination of H3 + n[PMo12 − nVnO 40]·aq (HPA-n, n = 3) and dioxygen provides a clean and regioselective reagent for the homolytic cleavage of various representative α-hydroxy ketones (primary to tertiary) and turns out to be as efficient for the catalytic ring opening of chiral natural products.

Graphical abstract: Efficient and selective catalytic oxidative cleavage of α-hydroxy ketones using vanadium-based HPA and dioxygen

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Article information

DOI
https://doi.org/10.1039/B106969A
Article type
Communication
Submitted
02 Aug 2001
Accepted
18 Aug 2001
First published
05 Oct 2001

Chem. Commun., 2001, 2218-2219

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Efficient and selective catalytic oxidative cleavage of α-hydroxy ketones using vanadium-based HPA and dioxygen

L. El Aakel, F. Launay, A. Atlamsani and J. Brégeault, Chem. Commun., 2001, 2218 DOI: 10.1039/B106969A

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