Issue 20, 2001
From the journal:

Chemical Communications

The first isolable pentacoordinate 1,2λ5-azaphosphetine: synthesis, X-ray crystallographic analysis, and dynamic behaviour

Naokazu Kano,a   Azusa Kikuchia  and  Takayuki Kawashima*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, Japan.
E-mail: takayuki@chem.s.u-tokyo.ac.jp;
Fax: +81 3 5800 6899;
Tel: +81 3 5841 4338

Abstract

Cycloaddition reaction of an iminophosphorane bearing the Martin ligand with an alkyne gave the first stable 1,2λ5-azaphosphetine, whose structure was determined by X-ray crystallographic analysis, and variable temperature NMR spectroscopy revealed the existence of equilibrium with the corresponding α-iminoalkylidenephosphorane.

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Article information

DOI
https://doi.org/10.1039/B106501G
Article type
Communication
Submitted
20 Jul 2001
Accepted
13 Sep 2001
First published
01 Oct 2001

Chem. Commun., 2001, 2096-2097

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The first isolable pentacoordinate 1,2λ5-azaphosphetine: synthesis, X-ray crystallographic analysis, and dynamic behaviour

N. Kano, A. Kikuchi and T. Kawashima, Chem. Commun., 2001, 2096 DOI: 10.1039/B106501G

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