Issue 20, 2001

Stereoselective preparation of highly functionalized (Z)-3-magnesiated enoates by an iodine–magnesium exchange reaction

Abstract

3-Iodoenoates are converted into the corresponding alkenylmagnesium species with complete retention of configuration of the double bond; both direct reaction and copper(I)-mediated reactions with various electrophiles provide polyfunctional enoates.

Article information

Article type
Communication
Submitted
12 Jul 2001
Accepted
05 Sep 2001
First published
27 Sep 2001

Chem. Commun., 2001, 2068-2069

Stereoselective preparation of highly functionalized (Z)-3-magnesiated enoates by an iodine–magnesium exchange reaction

I. Sapountzis, W. Dohle and P. Knochel, Chem. Commun., 2001, 2068 DOI: 10.1039/B106195J

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