Issue 20, 2001
From the journal:

Chemical Communications

The first Ru(ii)-catalysed asymmetric hydrogen transfer reduction of aromatic ketones in aqueous media

Hae Yoon Rhyoo,a   Hee-Jung Parka  and  Young Keun Chung*a  

* Corresponding authors

a School of Chemistry and Center for Molecular Catalysis, Seoul National University, Seoul, Korea.
E-mail: ykchung@plaza.snu.ac.kr;
Fax: 82-2-889-1568;
Tel: +82-2-880-6662(Office)/880-6815(Lab.)

Abstract

The first water-soluble asymmetric hydrogen-transfer ruthenium(II) catalyst system consisting of [Ru(p-cymene)Cl2]2, (S)-proline amide, and sodium formate, which gives high conversion rates with high ee values up to 95.3% and is reusable, has been developed.

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Article information

DOI
https://doi.org/10.1039/B106130P
Article type
Communication
Submitted
04 Jul 2001
Accepted
05 Sep 2001
First published
27 Sep 2001

Chem. Commun., 2001, 2064-2065

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The first Ru(II)-catalysed asymmetric hydrogen transfer reduction of aromatic ketones in aqueous media

H. Y. Rhyoo, H. Park and Y. K. Chung, Chem. Commun., 2001, 2064 DOI: 10.1039/B106130P

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