Issue 21, 2001
From the journal:

Chemical Communications

Observation of a P/M interconversion of a gold–phosphine helicate via   31P NMR

Walter Schuh,a   Holger Kopacka,a   Klaus Wursta  and  Paul Peringer*a  

* Corresponding authors

a Institut für Allgemeine, Anorganische und Theoretische Chemie, Universität Innsbruck, Innrain 52a, Innsbruck, Austria.
E-mail: paul.peringer@uibk.ac.at

Abstract

Ligands containing P–CH2–CH2–P elements have been shown to form double-stranded helicates whose axis consists of gold atoms with Au⋯Au contacts; the interconversion of the P and M forms of the helicate [Au3(μ-pp2)2](OTf)3 (pp2 = PhP(CH2CH2PPh2)2) is monitored via   31P NMR.

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Article information

DOI
https://doi.org/10.1039/B106058A
Article type
Communication
Submitted
09 Jul 2001
Accepted
05 Sep 2001
First published
05 Oct 2001

Chem. Commun., 2001, 2186-2187

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Observation of a P/M interconversion of a gold–phosphine helicate via   31P NMR

W. Schuh, H. Kopacka, K. Wurst and P. Peringer, Chem. Commun., 2001, 2186 DOI: 10.1039/B106058A

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