Issue 19, 2001
From the journal:

Chemical Communications

Transition metal-catalysed acylation of α,β-unsaturated

Eiji Shirakawa,*a   Youko Yamamoto,a   Yoshiaki Nakao,b   Teruhisa Tsuchimotoa  and  Tamejiro Hiyama*b  

* Corresponding authors

a Graduate School of Materials Science, Japan Advanced Institute of Science and Technology, Asahidai, Tatsunokuchi, Ishikawa, Japan.
E-mail: shira@jaist.ac.jp

b Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto, Japan

Abstract

Acylstannanes were found to add to such α,β-unsaturated carbonyl compounds as enones or ynoates in the presence of a nickel or palladium catalyst to give 2-stannyl-4-oxoalk-2-enoates or 1,4-diketones, whereas the three component coupling between acylstannanes, enones and aldehydes provided 2-hydroxymethyl 1,4-diketones.

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Article information

DOI
https://doi.org/10.1039/B105832K
Article type
Communication
Submitted
03 Jul 2001
Accepted
08 Aug 2001
First published
13 Sep 2001

Chem. Commun., 2001, 1926-1927

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Transition metal-catalysed acylation of α,β-unsaturated carbonyl compounds with acylstannanes

E. Shirakawa, Y. Yamamoto, Y. Nakao, T. Tsuchimoto and T. Hiyama, Chem. Commun., 2001, 1926 DOI: 10.1039/B105832K

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