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Issue 17, 2001
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The inverse podant [Li3(NBut)3S}] + stabilises a single ethylene oxide OCH[double bond, length half m-dash]CH2 anion as a high- and low-temperature polymorph of [(thf)3Li3(OCH[double bond, length half m-dash]CH2){(NBu t)3S}]

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Abstract

A single ethylene oxide anion derived from the ether cleavage reaction of thf with ButLi is stabilised by the inverse podant [Li3(NBut)3S}] + to give a high- and a low-temperature polymorph with a considerable difference in conformation and packing.

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Article information


Submitted
20 Jun 2001
Accepted
25 Jul 2001
First published
14 Aug 2001

Chem. Commun., 2001, 1640-1641
Article type
Communication

The inverse podant [Li3(NBut)3S}] + stabilises a single ethylene oxide OCH[double bond, length half m-dash]CH2 anion as a high- and low-temperature polymorph of [(thf)3Li3(OCH[double bond, length half m-dash]CH2){(NBu t)3S}]

B. Walfort, S. K. Pandey and D. Stalke, Chem. Commun., 2001, 1640
DOI: 10.1039/B105429P

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