Issue 19, 2001
From the journal:

Chemical Communications

Steric effects on the mode of aggregation and reactivity of clusters formed from the lithiation of trisamidothiophosphates

Tristram Chivers,*a   Mark Krahn,a   Masood Parveza  and  Gabriele Schattea  

* Corresponding authors

a Department of Chemistry, University of Calgary, Calgary, Alberta, Canada
E-mail: chivers@acs.ucalgary.ca

Abstract

Lithiation of SP[N(H)R]3 with LiBun produces the dimers [(THF)LiSP(NR)(NHR)2]2 (R = Pri) or {[LiSP(NR)- (NHR)2][(THF)LiSP(NR)2(NHR)]}2 (R = But) with central Li2N2 or Li2S2 rings, respectively; further lithiation yields the dianion [SP(NR)2(NHR)]2− (R = Pri) or leads to sulfur extrusion when R = But.

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Article information

DOI
https://doi.org/10.1039/B105360B
Article type
Communication
Submitted
15 Jun 2001
Accepted
12 Aug 2001
First published
13 Sep 2001

Chem. Commun., 2001, 1922-1923

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Steric effects on the mode of aggregation and reactivity of clusters formed from the lithiation of trisamidothiophosphates

T. Chivers, M. Krahn, M. Parvez and G. Schatte, Chem. Commun., 2001, 1922 DOI: 10.1039/B105360B

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