Issue 24, 2001
From the journal:

Chemical Communications

The crystal structure and physical properties of β-(BDA-TTP)2FeCl4 [BDA-TTP = 2,5-bis(1,3-dithian-2-ylidene)-1,3,4,6-tetrathiapentalene]

Jun-ichi Yamada,*a   Takashi Toita,a   Hiroki Akutsu,a   Shin’ichi Nakatsuji,a   Hiroyuki Nishikawa,b   Isao Ikemotob  and  Koichi Kikuchi*b  

* Corresponding authors

a Department of Material Science, Faculty of Science, Himeji Institute of Technology, 3-2-1 Kouto, Kamigori-cho, Ako-gun, Hyogo, Japan
E-mail: yamada@sci.himeji-tech.ac.jp

b Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo, Japan

Abstract

The title charge-transfer (CT) salt exhibits metallic conducting behavior with a metal-to-insulator (MI) transition at 113 K, and its magnetic properties reveal that it is an antiferromagnet below the Néel temperature, TN = 8.5 K.

Graphical abstract: The crystal structure and physical properties of β-(BDA-TTP)2FeCl4 [BDA-TTP = 2,5-bis(1,3-dithian-2-ylidene)-1,3,4,6-tetrathiapentalene]

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Article information

DOI
https://doi.org/10.1039/B105264K
Article type
Communication
Submitted
14 Jun 2001
Accepted
29 Oct 2001
First published
09 Nov 2001

Chem. Commun., 2001, 2538-2539

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The crystal structure and physical properties of β-(BDA-TTP)2FeCl4 [BDA-TTP = 2,5-bis(1,3-dithian-2-ylidene)-1,3,4,6-tetrathiapentalene]

J. Yamada, T. Toita, H. Akutsu, S. Nakatsuji, H. Nishikawa, I. Ikemoto and K. Kikuchi, Chem. Commun., 2001, 2538 DOI: 10.1039/B105264K

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