Issue 21, 2001
From the journal:

Chemical Communications

Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H2 O)2](C(CN)3)4Cl2 (pn = 1,3-diaminopropane)Electronic supplementary information (ESI) available: detailed synthesis and X-ray crystallography of 1. See http://www.rsc.org/suppdata/cc/b1/b105231b/

Smaïl Triki,*a   Franck Thétiot,a   Jean Sala Pala,a   Stéphane Golhen,b   Juan M. Clemente-Juan,c   Carlos J. Gómez-Garcíac  and  Eugenio Coronadoc  

* Corresponding authors

a UMR CNRS 6521, Univ. de Bretagne Occidentale, BP 809, Brest Cedex, France.
E-mail: smail.triki@univ-brest.fr

b UMR CNRS 6511, Univ. de Rennes 1, Rennes Cedex, France

c Instituto de Ciencia Molecular, Univ. de Valencia, Dr. Moliner 50, Burjasot, Spain

Abstract

A new polynuclear copper(II) complex [Cu7(OH)6Cl2- (pn)6(H2O)2](C(CN)3)4 Cl2 with hydroxo-bridging ligands has been prepared; the centrosymmetric cluster cation can be described as two Cu4O3Cl distorted cubane units sharing one copper cation.

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Article information

DOI
https://doi.org/10.1039/B105231B
Article type
Communication
Submitted
14 Jun 2001
Accepted
12 Sep 2001
First published
05 Oct 2001

Chem. Commun., 2001, 2172-2173

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Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H2 O)2](C(CN)3)4Cl2 (pn = 1,3-diaminopropane)

S. Triki, F. Thétiot, J. S. Pala, S. Golhen, J. M. Clemente-Juan, C. J. Gómez-García and E. Coronado, Chem. Commun., 2001, 2172 DOI: 10.1039/B105231B

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