Issue 19, 2001
From the journal:

Chemical Communications

Stereoselective total synthesis of (+)-myriocin from d-mannose

Takeshi Oishi,a   Koji Andoa  and  Noritaka Chida*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi, Kohoku-ku, Yokohama, Japan
E-mail: chida@applc.keio.ac.jp

Abstract

The stereoselective total synthesis of myriocin 1 from D-mannose is described; the carbon framework with three contiguous chiral centers including a tetra-substituted carbon with nitrogen was effectively constructed using Overman rearrangement as the key reaction.

Graphical abstract: Stereoselective total synthesis of (+)-myriocin from d-mannose

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Article information

DOI
https://doi.org/10.1039/B104864N
Article type
Communication
Submitted
04 Jun 2001
Accepted
21 Aug 2001
First published
04 Sep 2001

Chem. Commun., 2001, 1932-1933

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Stereoselective total synthesis of (+)-myriocin from D-mannose

T. Oishi, K. Ando and N. Chida, Chem. Commun., 2001, 1932 DOI: 10.1039/B104864N

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