Issue 16, 2001
From the journal:

Chemical Communications

A cross-shaped Ag5Ti4 molecule based on a [Ag(C[triple bond, length half m-dash]N)4]3− core

Thomas Steina  and  Heinrich Lang*a  

* Corresponding authors

a Technische Universität Chemnitz, Fakultät für Naturwissenschaften, Institut für Chemie, Lehrstuhl für Anorganische Chemie, Straße der Nationen 62, Chemnitz, Germany.
E-mail: heinrich.lang@chemie.tu-chemnitz.de

Abstract

K3[Ag(C[triple bond, length half m-dash]N)4] (2) reacts with {[Ti](C[triple bond, length half m-dash]CR)2}AgOClO3 {R = SiMe3, 1a; R = Ph, 1b; [Ti] = (η5-C5H4SiMe3)2 Ti} in a 1∶4 molar ratio to produce the nonametallic Ag5Ti4 species [Ag(C[triple bond, length half m-dash]N→Ag{(RC[triple bond, length half m-dash]C)2[Ti]})4 ](ClO4) (R = SiMe3, 3a; R = Ph, 3b) in which four heterobimetallic titanium(IV)–silver(I) tweezer units, [{[Ti](C[triple bond, length half m-dash]CR)2}Ag]+, are bridged by a [Ag(C[triple bond, length half m-dash]N)4]3− core; the reaction chemistry of 3 is reported.

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Article information

DOI
https://doi.org/10.1039/B104841B
Article type
Communication
Submitted
04 Jun 2001
Accepted
29 Jun 2001
First published
26 Jul 2001

Chem. Commun., 2001, 1502-1503

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A cross-shaped Ag5Ti4 molecule based on a [Ag(C[triple bond, length half m-dash]N)4]3− core

T. Stein and H. Lang, Chem. Commun., 2001, 1502 DOI: 10.1039/B104841B

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